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Coatings, Radiation Curable

Specialty Chemicals Update Program

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Published December 2021

Radiation curable formulations, used in coatings, inks, adhesives, and electronics, are cross-linked by highintensity ultraviolet light or electron beam energy sources. The coating formulations differ from those used in conventional paints and coatings in that the diluent (solvent) and resin (film former) used in thermally cured coatings are replaced by a reactive liquid vehicle in which a pigment and other additives may be dispersed or dissolved.

Radiation curable products are used for a wide variety of applications, which vary in importance from region to region. In North America, the graphic arts sector (which includes overprint varnishes and inks) predominates, with coatings, adhesives, and other industries being of lesser importance. In Europe, the wood coatings and graphic arts markets account for about 80% of demand. The situation is different in Asia. Radiation curable film resists, printing plates, semiconductor resists, and color filter resists are used extensively for semiconductors, printed circuit boards, printing plates, and other components. In Japan, these uses account for 20–30% of the total market for radiation curable products. In India, about 80% of radiation curable products are used by ink manufacturers. In mainland China, the major uses of radiation curable products are in wood, bamboo, paper, and plastics coatings.

The following pie chart shows world consumption of radiation curable products:

UV/EB technology is used in a variety of industrial segments such as graphic arts, packaging, wood furniture, fiber optics, electronics, building panels, and automotive parts. UV light can come from mercury lamps, xenon lamps or light emitting diodes (LEDs), or EB energy starts a photochemical reaction in coatings, inks, or adhesives. These formulations are based on monomers, oligomers, photoinitiators, and additives, although spray applications generally require the use of organic solvents or water as a diluent to reduce viscosity. Radicals or cations, formed from the reaction of the radiation with the photoinitiator, act as catalysts to solidify, dry, harden, polymerize, or cross-link the liquid formulation. When the layers become thicker and more pigmented, EB accelerators can be used for curing coatings without photoinitiators. Radiation-cured coatings have gained importance, being favored by environmental regulations and technology developments compared with other coatings.

Some of the faster growing sectors for the radiation curable products industry are expected to be the following:

  • Waterborne UV coating systems as replacements for solventborne systems.
  • Portable curing systems, which allow the application of radiation curable coatings at job sites, especially wood and concrete floor refinishing.
  • Inkjet inks, which are deposited on textiles, magazines, and other goods on a short-run or custom basis.
  • Formulations cured by exposure to UV LED curing lamps, which are more energy efficient and environmentally friendly than conventional mercury lamps.
  • Stereolithography, a process where 3D parts are produced from photosensitive resins. The major use so far is in the manufacture of prototypes for medical and electromechanical systems. There is interest in producing small-scale production volumes as well.
  • Flexible food packaging (inks and adhesives).

Potential new markets include

  • Printed electronics, which include any electrical device that is manufactured by printing. UV curable inks and coatings are being developed that have the potential for widescale use in portable photovoltaics, electroluminescent displays, transdermal patches, and organic light emitting diodes (OLEDs).
  • Coil coatings, which are applied to strips of metal coil processed at very high speeds.
  • Automotive OEM coatings on interior plastics and textile use. UV radiation curables are already well established as coatings for headlamps.
  • Coatings formulated with nanoparticles, which improve certain properties like hardness for clear wood coatings.
  • Renewable raw materials, such as epoxy acrylates made from soybean oil or polyester acrylates made from dimerized fatty acids obtained from soybean or tall oils.

In recent years, the radiation curable industry has grown at rates higher than those of the overall coatings and inks markets. During the next five years, consumption of radiation curable coatings is expected to grow at an average annual rate of 4.5%.

For more detailed information, see the table of contents, shown below.

S&P Global’s Specialty Chemicals Update Program –Coatings, Radiation Curable is the comprehensive and trusted guide for anyone seeking information on this industry. This latest report details global and regional information, including

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S&P Global’s Specialty Chemicals Update Program –Coatings, Radiation Curable has been compiled using primary interviews with key suppliers and organizations, and leading representatives from the industry in combination with S&P Global’s unparalleled access to upstream and downstream market intelligence and expert insights into industry dynamics, trade, and economics.

This report can help you

  • Identify the competitive environment and key players
  • Assess key issues facing both suppliers and their end-use customers
  • Understand industry integration strategies
  • Keep abreast of industry structure changes, regulatory requirements, and other factors affecting profitability
  • Identify new business opportunities and threats
  • Follow important commercial developments
  • Recognize trends and driving forces influencing specialty chemical markets
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Contents

Executive summary 7
Summary 8
Introduction 12
Abbreviations 16
Radiation curable coating technology 18
Raw materials 18
Oligomers 18
Acrylates 18
Unsaturated polyesters 20
Thiol-enes 20
Cationic cure epoxies 21
Vinyl ethers 22
Reactive diluents or monomers 22
Monofunctional monomers 22
Styrene 23
Di-, tri-, and polyfunctional monomers 23
Photoinitiators 25
Free radical polymerization 25
Cationic polymerization 29
Additives 30
Solvents 30
Formulations 31
UV and EB curing processes 33
Ultraviolet (UV) curing 34
Electron beam (EB) curing 37
Overview of the radiation curable coatings industry 41
Structure of the industry 41
Suppliers of raw materials 43
North America 43
Europe 44
Mainland China 46
Japan 51
South Korea and Taiwan 54
Formulators of radiation curable coatings 56
North America 56
Europe 57
Mainland China 60
Japan 62
South Korea and Taiwan 65
Southeast Asia and India 65
Profiles of selected producers in the radiation curable coatings industry 66
Allnex 66
BASF 69
Chongqing Changfeng Chemical 71
Covestro 71
Eternal Materials 72
Miwon Specialty Chemical 73
DIC 73
IGM Resins 75
Jiangsu Sanmu Group 76
T&K TOKA 76
Sartomer 77
Mergers and acquisitions 79
Equipment suppliers 80
Operating characteristics 83
Research and development 83
Raw materials 84
Oligomers 84
Reactive diluents (monomers) 85
Photoinitiators 85
Dual-cure systems 85
Waterborne systems 86
Manufacturing 87
Marketing 87
Cost structure 88
Government regulations 90
North America 91
Toxicity 91
Air pollution 91
Food packaging 92
Sustainability 92
Europe 93
REACH 93
Toxicity concerns 95
Air pollution 95
Food contact directive 96
Mainland China 97
Japan 98
Future trends and opportunities 98
Raw materials 99
Raw material availability 99
Curing of 3D objects 100100
Waterborne systems 100
Nanoparticles 100
UV LED lamps 101
Portable curing systems 103
Renewable raw materials 105
Printed electronics 106
Composites and others 107
Aircraft 108
Critical factors for success 109
Markets 112
Regional markets 112
Raw materials for radiation curable coatings 115
North America 118
Central and South America 121
Europe 121
Mainland China 124
Japan 126
Other Asia 128
South Korea and Taiwan 128
Southeast Asia and India 128
Product markets 129
Paper and film coatings 129
Overprint varnishes 129
Silicone release liners 131
Printing inks 132
Inkjet inks 135
UV curable toners 138
Wood 139
UV powder coatings 142
Plastics 144
Vinyl flooring 144
Automotive lenses and other parts 145
Mobile phones and electronic devices 146
Other 147
Electronic products 148
Photolithography 148
Optical fibers 149
Optical discs/DVDs/CDs 150
Adhesives 151
Metal coatings 155
Containers 155
Automotive 156
Coil coatings 157
Piping and tubing 158
Other metal parts 159
Other 159
Photovoltaic coatings 159
Stereolithography (3D printing) 159159
Other 163
Prices 163
Revisions 167
Data Workbook 168
Notice 169

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Eric Linak
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