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Dimethyl Terephthalate (DMT) and Terephthalic Acid (TPA)

Chemical Economics Handbook

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Published September 2023

Terephthalic acid (TPA) and dimethyl terephthalate (DMT) are consumed primarily to produce linear, saturated polyester resins, fibers and films by reaction with glycols. Nearly all worldwide consumption of TPA and DMT is for the production of intermediate polyethylene terephthalate (PET) polymer. PET polymer, also referred to as reactor-grade polyester or PET melt-phase resin, is consumed primarily in the production of polyester fibers, polyester film and solidstate (bottle-grade) resins. TPA has lower capital costs and better manufacturing economics and, therefore, is the preferred feedstock for nearly all terephthalate applications.

The following chart presents world consumption of TPA/DMT:

Asia is the largest consumer of TPA/DMT, although consumption is almost entirely TPA. Mainland China is and will remain the largest global market for TPA. Asia will also account for most of the world’s TPA/DMT consumption growth in the next five years.

Polyester melt polymer accounts for almost all TPA/DMT consumption. The manufacture of polybutylene terephthalate (PBT), polytrimethylene terephthalate (PTT), dioctyl terephthalate and other minor products such as cyclohexanedimethanol (CHDM), terephthaloyl chloride and copolyester-ether elastomers accounts for the remainder. Increasing demand for polyester fibers will drive future consumption of TPA/DMT. Its ample availability, advantaged cost position and performance characteristics relative to competing materials have positioned polyester fibers to take the largest share of global man-made fiber consumption growth.

During 2017–22, consumption of TPA grew at nearly 5% per year, while the DMT market declined at more than 1% per year. Consumption of DMT will continue to decline in favor of TPA. The increase in TPA consumption will be mainly driven by the growing PET resin and fiber markets in mainland China, India, the United States, Southeast Asia and the Middle East.

There is interest in recycling PET, especially when virgin polymer prices are relatively high. The portion of PET that is recycled is high compared with most other resins. Most recycled PET is utilized as waste polymer for reprocessing, but processes have also been developed to chemically regenerate monomers or oligomers. The impetus for development of these processes is the assumption that chemical intermediates will find acceptability in a broader range of highervalue-added applications. Although there is significant capacity for regeneration, the amount of PET reprocessed is much smaller than the amount that is recycled as resin.

For more detailed information, see the table of contents, shown below.

S&P Global’s Chemical Economics Handbook – Dimethyl Terephthalate (DMT) and Terephthalic Acid (TPA) comprehensive and trusted guide for anyone seeking information on this industry. This latest report details global and regional information, including

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S&P Global’s Chemical Economics Handbook – Dimethyl Terephthalate (DMT) and Terephthalic Acid (TPA) has been compiled using primary interviews with key suppliers and organizations, and leading representatives from the industry in combination with S&P Global’s unparalleled access to upstream and downstream market intelligence and expert insights into industry dynamics, trade and economics.

This report can help you

  • Identify trends and driving forces influencing chemical markets
  • Forecast and plan for future demand
  • Understand the impact of competing materials
  • Identify and evaluate potential customers and competitors
  • Evaluate producers
  • Track changing prices and trade movements
  • Analyze the impact of feedstocks, regulations, and other factors on chemical profitability
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Contents

Executive summary 5
Summary 6
Salient statistics 6
Capacity 8
Consumption 10
Consumption forecast 12
Trade 13
Introduction 18
Manufacturing processes 20
Processes based on para-xylene 20
Dimethyl terephthalate 20
Witten process 20
Other processes 21
Regeneration 22
Terephthalic acid 23
Amoco process 23
Other processes 23
Processes based on toluene 24
Supply and demand by region 25
North America 25
Overview 25
Salient statistics 25
Consumption 26
United States 28
Producing companies 28
Salient statistics 29
Consumption 30
Polyester melt 31
Polyester engineering resins 32
Polytrimethylene terephthalate (PTT) 32
Other 32
Trade 33
Canada 33
Producing companies 33
Salient statistics 34
Consumption 35
Trade 35
Mexico 35
Producing companies 35
Salient statistics 36
Consumption 37
Trade 38
Central and South America 38
Producing companies 38
Salient statistics 39
Consumption 40
Trade 40
Western Europe 40
Producing companies 40
Salient statistics 42
Consumption 43
Trade 44
Central and Eastern Europe 45
Producing companies 45
Salient statistics 45
Consumption 46
Trade 47
CIS and Baltic States 47
Producing companies 47
Salient statistics 48
Consumption 50
Trade 51
Middle East 51
Producing companies 51
Salient statistics 53
Consumption 54
Trade 55
Africa 55
Producing companies 55
Salient statistics 55
Consumption 56
Trade 57
Indian Subcontinent 57
Producing companies 57
Salient statistics 58
Consumption 60
Northeast Asia 61
Overview 61
Salient statistics 61
Consumption 63
Mainland China 65
Producing companies 65
Salient statistics 67
Consumption 69
PET 70
PBT 70
PTT 70
Plasticizers 71
Trade 71
Japan 71
Producing companies 71
Salient statistics 72
Consumption 73
Trade 74
South Korea 74
Producing companies 74
Salient statistics 75
Consumption 77
Trade 78
Taiwan 78
Producing companies 78
Salient statistics 79
Consumption 81
Trade 82
Southeast Asia 82
Producing companies 82
Salient statistics 83
Consumption 84
Trade 85
Additional resources 86
Revisions 87
Data Workbook 88

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