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Costs of Synthesis Gases and Methanol

Process Economics Program Report 148

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Published February 1983

Costs of Synthesis Gases and Methanol, Part 1 (PDF, 11 MB)

Costs of Synthesis Gases and Methanol, Part 2 (PDF, 16 MB)

View Table of Contents, Part 2 (PDF, 701 KB)

Mixtures of carbon monoxide and hydrogen, commonly known as syngases, are produced on an enormous scale for the manufacture of ammonia, hydrogen, methanol, and other chemicals. Less traditional uses of syngases continue to be developed and have increased in importance in recent years, viz., acetic acid and acetic anhydride manufacture. Among the promising new developments in syngas chemistry are routes to ethylene.

The syngas routes may be attractive in themselves, irrespective of raw materials, or they may provide the option to use alternative and ultimately cheaper raw materials such as coal and, in certain circumstances, natural gas. The search for alternative feedstocks has been given considerable impetus by the fact that for petroleum based commodity chemicals, feedstock costs now compose the major part of the product value. An added attraction of syngas is that it can be manufactured from almost any raw material containing carbon; hence the availability of feedstocks is ensured. The developments in syngas chemistry have the potential for radical impacts on the chemical industry. They open the door to the possible return of the industry to is traditional position-a capital intensive industry adding a high value to a low cost feedstock.

The cost of syngas can be highly variable, depending on hydrogen/ carbon monoxide ratio, raw material and process, scale of operation and extent of integration with other processes, cost of CO2, credit for hydrogen, and so on. Often, the syngas routes are indirect, proceeding via methanol and including a carbonylation step using carbon monoxide per se. In addition, over the past decade, cost components have escalated at widely different rates, sometimes with large step changes. A frequent problem for analysis in this area has thus been the lack of readily available data for current and representative costs of syngases and related products. To serve this need we therefore developed a flexible and easily updated computer model called SYNCOST, which calculates the costs of syngas and related products.

Other PEP Related Reports:

  • Synthesis Gas 148A
  • Synthesis Gas Production from Natural Gas Reforming 148B
  • Synthesis Gas Production from Coal and Petroleum Coke Gasification 148C
  • Synthesis Gas Production from Chinese Gasifiers 148D
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Table of Contents

Section Page Number

SYNGASES, HYDROGEN, AND METHANOL FROM THE STEAM REFORMING OF NATURAL GAS1
Chemistry of Steam Reforming 4
Discussion of the Assumed Technical Basis 8
Steam Reforming Stage 11
Carbon Dioxide Separatioin 19
Flue Gas Scrubbing 24
Hydrogen Production 24
Methanol Production 25
H2:CO Ratio Adjustment by Separation Processes 30
Values Assigned to Steam 34
Process Description 37
Cases A and B: Syngas Streams with H2:CO Ratios of 3:l and 2:l Obtained by CO2 Addition to Reformer Feed 37
Case C: Hydrogen by Conventional Steam Reforming of Natural Gas (Including CO Shift Stages and Methanation) 44
Case D: Methanol from Natural Gas by ICI Low Pressure Process (High Efficiency Design) 47
Separation Processes for Adjusting H2:CO Ratio 54
Cryogenic Separation by Liquid Methane Wash 54
Pressure Swing Adsorption (PSA) 55
Tenneco's Cosorb® System56
Monsanto's Prism®' Separators 58
Cost Estimates 59
Basic Cases 59
Syngas H2:CO Ratio Adjustment by H2 Skimming 62
Costs of Syngas Compression 92
Effect of Scale of Operation 98
SYNGASES AND HYDROGEN BY THE PARTIAL OXIDATION OF VACUUM RESIDUE 123
Brief Description of Cases Examined 124
Chemistry 128
Characterization of Partial Oxidation Reactor Performance 129
Brief Review of Processes 132
Partial Oxidation Stage 132
Acid Gas Removal System 134
Sulfur Recovery 135
Process Description 135
Cost Estimates 141
COAL GASIFICATION 149
Historic Development 152
Technical Background 154
General Considerations 154
Variability of Coal 155
Temperature Constraints 159
Gasification Pressure 160
Flow Characteristics 161
Fixed Bed 164
Fluidized Bed 165
Entrained Flow 166
Stoichiometric Considerations 167
Selection of Base Case for Cost Evaluation 178
Base Case Design--Methanol from Coal 182
Overall Plant Design 182
Process Description 191
Process Discussion 195
Gasification 195
Shift, COS Hydrolysis, and Acid Gas Removal 196
Methanol Synthesis and Refining 197
Cost Estimates--Methanol from Coal 198
Capital Investment 198
Production Costs and Product Value 204
ROI and Profitability 206
Discussion of Costs 208
Derived Cost Modules214
Rationale for Cost Allocations 214
Methanol-from-Syngas Unit 216
Syngases of Various H2:CO Ratios, and Hydrogen 217
1. Methanol Syngas from Coal (Module 13) 220
2. Methanol from Coal-Derived Syngas (Module 27) 223
3. Syngas (H2 :CO = 0.75) from Coal (Module 1) 226
4. Syngases H2:CO = 1.0, 1.5, 2.0)from Coal (Modules 2, 7, 8) 231
5. Hydrogen from Coal (Module 22) 234
Conclusions 238
CARBON MONOXIDE SEPARATION FROM SYNGAS 267
Main Features of'separation Modules 271
Cost Estimates 278
CITED REFERENCES 293
PATENT REFERENCES 299

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