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Alkyd/Polyester Surface Coatings

Chemical Economics Handbook

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Published August 2023

Alkyd surface coatings continue to be one of the most highly consumed types of coatings used in the world, despite the increasing use of other film formers. The success of alkyd resin systems is a result of their relatively low cost, versatility and long familiarity with users. They can be tailored to meet a variety of end-use requirements through the choice and ratio of reactants and/or modifiers. Alkyds are used extensively in architectural coatings, product finishes and special-purpose coatings. Promoters of alkyd resins note that they are partly made from fatty acids or oils derived from renewable sources, making them greener than most competitive coating resins. Alkyds were the first synthetic coatings binder used in commercial practice, first used in large quantities in the 1930s.

Polyesters, also referred to as oil-free alkyds, are made in the same equipment as alkyds and use many of the same raw materials. Polyesters are used almost exclusively in industrial baking finishes.

The following pie chart shows world consumption of alkyd/polyester surface coatings:

Despite the continuing decline in the market in North America, Western Europe, and Japan, alkyds remain one of the leading types of coatings used in the industrial marketplace.

In North America, Western Europe, and Japan, consumption of alkyds has diminished over the last 40 years. In the architectural or decorative coatings market, solventborne alkyds have been steadily replaced with waterborne emulsions because of their lower odor, lower solvent content, easy clean-up and fast drying properties. However, in some applications, these emulsions do not display the same degree of performance in leveling, adhesion, gloss and certain resistance properties. These drawbacks have stalled the conversion from most solventborne gloss trim, wood stains and light maintenance coatings, so solventborne alkyds remain a sizable factor in the coatings industry.However, restrictions on the use of paints are becoming tighter in certain parts of the United States and in Europe, which will forbid the use of conventional low-solids (i.e., high-solvent-containing) solventborne coatings.

As a result, the types of resins used in these regions in certain applications will change significantly. Most use of polyester coatings in the United States is in metal furniture, construction, appliances and transportation businesses that are mature and grow at GDP-like rates. Growth is expected to be 3.0% annually during 2020–15 as the United States recovers from the COVID-19 pandemic.

Producers continue to develop new and improved systems for high-solids and waterborne formulations to meet increasingly stringent air pollution regulations. In recent years, producers of alkyd resins have developed waterborne latex resins that meet the low VOC levels required by recently enacted legislation in certain parts of the United States and Western Europe. Generally, though, these environmentally friendly systems are considerably more expensive than the conventional systems, and have some technical drawbacks. Polyesters are offered in high-solids, waterborne and powder coatings, which are more environmentally acceptable.

Mainland China is the fastest-growing region in the world, and some multinational producers of resins and coatings have established production facilities here. In particular, the use of alkyd coatings for construction applications and of polyester-epoxy hybrid powder coatings on metal parts has grown rapidly.

Global consumption of alkyd coating resins and alkyd coatings is forecast to grow at an average annual rate of about 3% during 2020–25. Average annual growth in the consumption of polyester coating resins and polyester coatings will be 5% during 2020–25.

For more detailed information, see the table of contents, shown below.

S&P Global’s Chemical Economics Handbook –Alkyd-Polyester Surface Coatings is the comprehensive and trusted guide for anyone seeking information on this industry. This latest report details global and regional information, including

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S&P Global’s Chemical Economics Handbook –Alkyd-Polyester Surface Coatings has been compiled using primary interviews with key suppliers and organizations, and leading representatives from the industry in combination with S&P Global’s unparalleled access to upstream and downstream market intelligence and expert insights into industry dynamics, trade and economics.

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  • Track changing prices and trade movements
  • Analyze the impact of feedstocks, regulations, and other factors on chemical profitability
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Table of contents

Executive summary 6
Summary 7
Introduction 11
Raw materials 12
Alkyds 12
Polybasic acids and anhydrides 12
Phthalic anhydride 12
Isophthalic acid 12
Maleic anhydride 12
Terephthalic acid 12
Other 12
Polyhydric alcohols 13
Pentaerythritol 13
Glycerin 13
Other 13
Monobasic acids 14
Vegetable oils 14
Soybean oil 14
Linseed oil 15
Castor oil 15
Other 15
Tall oil fatty acids 15
Marine oils 15
Synthetic fatty acids 15
Alkyds and polyesters from renewable resources 16
Modifiers 17
Chemically modified alkyds 17
Isocyanates 17
Styrene and vinyl toluene 17
Acrylic monomers 17
Rosin and rosin esters 17
Benzoic acid and derivatives 18
Blends of alkyds with other resins 18
Chlorinated rubber 18
Nitrocellulose 18
Phenolics 18
Silicone 18
Polyamide (nonnylon type) 18
Other 18
Sample resin formulations 19
Polyesters 21
Manufacturing processes 23
Coating formulation 23
Pigments 24
Solvents 24
Additives 24
Driers 24
Other 25
Environmentally acceptable formulations 25
Solventborne alkyds using exempt solvents 26
High-solids alkyds 27
Waterborne alkyds 27
Modifying alkyds 29
High-solids polyesters 29
Waterborne polyesters 30
Powder coatings 30
Environmental issues 31
United States 31
Western Europe 33
Japan 34
Supply and demand by region 35
United States 35
Producing companies 35
Production 39
Consumption 40
Architectural coatings 42
Exterior 44
Interior 45
Product finishes — OEM 46
Metal furniture and fixtures 47
Appliances 47
Sheet, strip and coil 47
Machinery and equipment 48
Transportation 49
Wood furniture and fixtures 50
Electrical insulation (varnishes and magnet wire enamels) 51
Containers 52
Wood and composition flat stock 52
Other 53
Special-purpose coatings 53
Industrial maintenance 53
Aerosols 54
Traffic paints 55
Automotive refinishing 55
Price 56
Resins 56
Coatings 56
Trade 57
Canada 58
Mexico 59
South America 61
Europe 64
Producing companies 64
Production 70
Consumption 74
Architectural coatings 76
Product finishes — OEM 78
Special-purpose coatings 81
Price 82
Resins 82
Coatings 85
Trade 88
Eurasia 88
Producing companies 89
Production 89
Consumption 89
Architectural coatings 90
OEM product finishes 90
Trade 91
Middle East and Africa 91
Producing companies 91
Consumption 93
Architectural coatings 93
Product finishes 93
Trade 94
Mainland China 94
Producing companies 94
Production 98
Consumption 98
Price 99
Trade 100
Japan 101
Producing companies 101
Salient statistics 103
Consumption 104
Price 107
Trade 107
Other Asia and Oceania 108
Producing companies 108
Salient statistics 112
South Korea 117
Taiwan 120
South Asia, Southeast Asia and Oceania 121
Additional resources 124
Revisions 125
Data Workbook 126

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