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Chlorine

Process Economics Program Report 61

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Published April 1970

This report deals with processes for the manufacture of chlorine. Processes evaluated are aqueous salt electrolyisis, hydrochloric acid electrolyisis, two processes of hydrogen chloride oxidation using a hetrogenous catalyst and nitric acid, respectively, and ammonium chloride oxidation. In connection with the last mentioned process, the process for coproduction of ammonium chloride in soda ash manufacture is evaluated and compared with the conventional Solvay Process. Two variations of the aqueous salt electrolysis process are also evaluated, one resulting in soda ash instead of caustic soda and the other integrating with a Solvay plant.

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