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Fluorspar, Fluorosilicic Acid (FSA), Hydrofluoric Acid (HF) and Inorganic Fluorine Chemicals

Chemical Economics Handbook

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Published July 2023

This report covers fluorspar and its major derivative, hydrofluoric acid, as well as providing additional data on aluminum fluoride, cryolite and fluorosilicic acid. Fluorspar is a mineral from which more than 95% of all fluorine-based compounds are derived. Hydrofluoric acid is the most important chemical derived from fluorspar and accounts for more than half of global fluorspar consumption in 2023, followed by use for aluminum smelting and steel manufacturing.

Although 20 countries have the ability to produce significant quantities of fluorspar, the majority of the world’s fluorspar production has become concentrated in mainland China, which accounted for more than half of world production in 2022. The next-largest producers are North America (Mexico), Mongolia, and Africa. Historically, the majority of mainland China’s fluorspar production was exported, but after a decade of building and growing its fluorinebased chemical industry, mainland China adds value to its domestic acid-spar supply through the production of downstream products such as hydrofluoric acid, fluorocarbons and fluoropolymers, rather than exporting the mineral.

The following pie chart shows world consumption of fluorspar:

World demand for fluorspar will grow at an average annual rate of about 2%-3% during 2023–28.

Hydrofluoric acid is the major end use market for fluorspar, accounting for more than half of fluorspar consumption in 2023. The following pie chart shows world consumption of hydrofluoric acid:

Hydrofluoric acid is the raw material for the production of fluorocarbons, which are used in refrigeration and air conditioning, and as a precursor to fluoropolymers and elastomers. In addition, hydrofluoric acid serves as a catalyst in petroleum alkylation, a process used for gasoline manufacture. It is also used in metal treatment, uranium fuel production and as a raw material in the manufacture of inorganic fluorine compounds, including most inorganic fluorides as well as elemental fluorine. Many changes are looming in the fluorocarbon industry over the next 15 years, as hydrochlorofluorocarbons (HCFCs) are being restricted and gradually substituted by gases with a lower global warming potential.

For more detailed information, see the table of contents, shown below.

S&P Global’s Chemical Economics Handbook – Fluorspar, Fluorosilicic Acid (FSA), Hydrofluoric Acid (HF) and Inorganic Fluorine Compounds is the comprehensive and trusted guide for anyone seeking information on this industry. This latest report details global and regional information, including

Key benefits

S&P Global’s Chemical Economics Handbook – Fluorspar, Fluorosilicic Acid (FSA), Hydrofluoric Acid (HF) and Inorganic Fluorine Compounds has been compiled using primary interviews with key suppliers and organizations, and leading representatives from the industry in combination with S&P Global’s unparalleled access to upstream and downstream market intelligence and expert insights into industry dynamics, trade and economics.

This report can help you

  • Identify trends and driving forces influencing chemical markets
  • Forecast and plan for future demand
  • Understand the impact of competing materials
  • Identify and evaluate potential customers and competitors
  • Evaluate producers
  • Track changing prices and trade movements
  • Analyze the impact of feedstocks, regulations and other factors on chemical profitability
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Table of Contents

Section Page Number

Executive summary 8
Summary 10
Fluorspar 10
Reserves and resources 11
Production 13
Consumption 16
Hydrofluoric acid 19
Capacity 20
Consumption 22
Lithium hexafluorophosphate 25
Aluminum fluoride 27
Fluorosilicic acid 30
Introduction 32
Manufacturing processes 33
Fluorspar 33
Fluorosilicic acid/silicofluoride salts 33
Hydrogen fluoride/hydrofluoric acid 34
Environmental issues 35
United States 35
European Union 38
Mainland China 39
Japan 39
Hydrofluoric acid recycling, disposal and recovery of by-products 40
Supply and demand by region 42
Fluorspar 42
United States 42
Producing companies 42
Salient statistics 42
Consumption 43
Hydrofluoric acid 45
Steel 45
Aluminum fluoride 46
Glass 46
Iron and steel castings 46
Other 47
Price 47
Trade 48
Imports 48
Exports 49
Canada 50
Producing companies 50
Salient statistics 50
Consumption 51
Price 52
Trade 52
Mexico 54
Producing companies 54
Salient statistics 54
Production 55
Consumption 56
Trade 57
South America 58
Producing companies 58
Salient statistics 59
Production 60
Consumption 60
Trade 61
Western Europe 63
Producing companies 63
Salient statistics 64
Consumption 66
Price 67
Trade 68
Imports 68
Exports 70
Central and Eastern Europe 71
Producing companies 71
Salient statistics 72
Production 73
Consumption 73
Price 74
Trade 75
Middle East 76
Producing companies 76
Salient statistics 76
Production 77
Consumption 78
Trade 79
Africa 80
Producing companies 80
Salient statistics 82
Production 82
Consumption 83
Trade 84
Mainland China 86
Producing companies 88
Salient statistics 90
Consumption 94
Price 96
Trade 97
Imports 97
Exports 98
Japan 99
Producing companies 99
Salient statistics 99
Consumption 100
Price 101
Trade 102
Mongolia 104
Producing companies 104
Production 105
Consumption 105
Trade 106
India 107
Producing companies 107
Salient statistics 107
Consumption 108
Trade 109
Other Asia and Oceania 110
Producing companies 110
Salient statistics 111
Consumption 112
Trade 113
Other fluorine minerals 115
Hydrofluoric acid 115
United States 115
Producing companies 115
Salient statistics 116
Consumption 118
Fluorocarbon production 119
Metal treatment 121
Petroleum alkylation catalysis 121
Uranium fuel production 122
Lithium hexafluorophosphate 122
Other 122
Price 123
Trade 123
Canada 124
Producing companies 124
Salient statistics 125
Consumption 125
Trade 126
Mexico 127
Producing companies 127
Salient statistics 128
Consumption 128
Trade 129
South America 130
Producing companies 130
Salient statistics 130
Consumption 130
Trade 132
Western Europe 133
Producing companies 133
Salient statistics 135
Production 136
Consumption 136
Fluorocarbons 138
Fluoroaromatics 140
Aluminum fluoride/sodium aluminum fluoride 140
Fluorine 140
Uranium hexafluoride 140
Lithium hexafluorophosphate 141
Other 141
Price 143
Trade 143
Central and Eastern Europe 144
Producing companies 144
Salient statistics 145
Production 146
Consumption 147
Trade 149
Middle East 150
Producing companies 150
Salient statistics 150
Production 151
Consumption 152
Trade 153
Africa 154
Producing companies 154
Salient statistics 155
Production 155
Consumption 156
Trade 157
Mainland China 158
Producing companies 158
Salient statistics 160
Consumption 161
Fluorocarbons 162
Lithium hexafluorophosphate 163
Electronic specialty gases 165
Other 166
Price 166
Trade 166
Japan 167
Producing companies 167
Salient statistics 168
Consumption 169
Fluorocarbon production 170
Fluoboric acid and fluoborates 171
Nitrogen trifluoride 172
Lithium hexafluorophosphate 173
India 173
Producing companies 173
Salient statistics 174
Consumption 175
Other Asia and Oceania 177
Producing companies 177
Salient statistics 178
Consumption 179
Trade 181
Aluminum fluoride/cryolite 185
United States 185
Producing companies 185
Salient statistics 185
Consumption 186
Trade 187
Canada 188
Producing companies 188
Salient statistics 188
Consumption 189
Trade 190
Mexico 192
Producing companies 192
Salient statistics 192
Consumption 193
Trade 194
South America 195
Producing companies 195
Salient statistics 195
Consumption 197
Trade 198
Western Europe 200
Producing companies 200
Salient statistics 202
Consumption 203
Trade 205
Central and Eastern Europe 205
Producing companies 205
Salient statistics 206
Consumption 208
Trade 209
Middle East 211
Producing companies 211
Salient statistics 212
Consumption 214
Trade 215
Africa 216
Producing companies 216
Salient statistics 217
Consumption 218
Trade 219
Mainland China 220
Producing companies 220
Salient statistics 221
Consumption 223
Price 225
Trade 226
Japan 226
India 227
Other Asia and Oceania 231
Fluorosilicic acid 232
United States 233
Brazil 236
Western Europe 237
Producing companies 237
Salient statistics 238
Consumption 239
Price 241
Trade 241
Central and Eastern Europe 242
Middle East 245
Mainland China 248
Japan 250
India 251
Other Asia and Oceania 252
Additional resources 253
Revisions 254
Data Workbook 255

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