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MTBE, ETBE and Other Octane Improvers

Chemical Economics Handbook

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Published December 2022

This report covers the five major chemicals used to improve gasoline octane ratings—fuel ethanol, methyl tertiary-butyl ether (MTBE), methanol, ethyl tertiary-butyl ether (ETBE), and tertiary-amyl methyl ether (TAME). Worldwide, the leading gasoline octane improvers are fuel ethanol, MTBE, methanol (primarily in mainland China), and then ETBE. TAME is the smallest of the major octane improvers.

The following chart shows world consumption of gasoline octane improvers/oxygenates by type:

After ethanol, the second leading gasoline octane improver/oxygenate is MTBE. Starting in the late 1970s, MTBE was the predominant choice of gasoline oxygenate used worldwide because of its low cost, high octane value, and easy incorporation into gasoline stock. However, in the late 1990s, MTBE was alleged to cause detrimental environmental impact by contaminating water supplies. As a result, the use of MTBE as an oxygenate in gasoline ceased in Japan in 2001 and in the United States and Canada in 2006. MTBE is still widely used as an octane booster in motor gasoline in Europe, the Middle East, Africa, and Asia.

The United States still produces MTBE, but mainly for the export market or for blending into gasoline for export. There are several large Latin American consumers of MTBE (such as Mexico and Venezuela) that import considerable quantities from the United States. Both have made some plans to use more ethanol or ETBE to reduce greenhouse gases (GHGs).

The third-largest-volume gasoline octane improver/oxygenate used in the world is methanol. Consumption is primarily in mainland China (greater than 95%), with smaller quantities being consumed in Western Europe, the Middle East, Africa, and Southeast Asia.

ETBE is consumed primarily in Western Europe and Japan, where the mandated use of biofuels is driving consumption for bioethanol-based ETBE.

For more detailed information, see the table of contents, shown below.

IHS Markit’s Chemical Economics Handbook – MTBE, ETBE, and Other Octane Improvers is the comprehensive and trusted guide for anyone seeking information on this industry. This latest report details global and regional information, including

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IHS Markit’s Chemical Economics Handbook – MTBE, ETBE, and Other Octane Improvers has been compiled using primary interviews with key suppliers and organizations, and leading representatives from the industry in combination with IHS Markit’s unparalleled access to upstream and downstream market intelligence and expert insights into industry dynamics, trade, and economics.

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Table of Contents

Executive summary8
Summary10
Methyl tertiary-butyl ether (MTBE) 14
Capacity 15
Salient statistics 16
Consumption 17
Price 18
Ethyl tertiary-butyl ether (ETBE) 19
Other oxygenates 20
Ethanol 20
Consumption 21
Methanol 22
tertiary-Butyl alcohol (TBA) 25
tertiary-Amyl methyl ether (TAME) 25
Dimethyl ether (DME) 26
Introduction27
Manufacturing processes30
Methyl tertiary-butyl ether (MTBE) 30
Ethyl tertiary-butyl ether (ETBE) 32
tertiary-Amyl methyl ether (TAME) 32
tertiary-Butyl alcohol (TBA) 33
Lead alkyl antiknock mixes 34
Environmental issues36
United States 36
Europe 36
Middle East and Africa 41
Asia 41
Supply and demand by region43
North America 43
Motor gasoline production and oxygenate demand 43
Methyl tertiary-butyl ether (MTBE) 44
Producing companies 44
Salient statistics 45
Consumption 46
Trade 47
Ethyl tertiary-butyl ether (ETBE) 47
Other oxygenates 49
Ethanol 49
Methanol 52
tertiary-Amyl methyl ether (TAME) 53
tertiary-Butyl alcohol (TBA) 53
Diisopropyl ether (isopropyl ether, DIPE) 54
Other ethers 54
Central and South America 54
Motor gasoline and oxygenate demand 54
Methyl tertiary-butyl ether (MTBE) 56
Producing companies 56
Salient statistics 56
Consumption 57
ETBE 58
Other oxygenates 59
Ethanol 59
Western Europe 59
Motor gasoline characteristics in the European Union (EU) region 59
Motor gasoline and oxygenate demand 60
Methyl tertiary-butyl ether (MTBE) 62
Producing companies 62
Salient statistics 63
Consumption 63
Ethyl tertiary-butyl ether (ETBE) 65
Producing companies 65
Salient statistics 66
Consumption 66
Trade 67
Other oxygenates 67
Ethanol 67
Consumption 67
Methanol 68
tertiary-Amyl methyl ether (TAME) 68
tertiary-Butyl alcohol (TBA) 68
Central and Eastern Europe 69
Motor gasoline and oxygenate demand 69
Methyl tertiary-butyl ether (MTBE) 71
Producing companies 71
Salient statistics 71
Consumption 72
ETBE 73
Other oxygenates 74
Ethanol 74
Methanol 74
CIS and Baltic States 74
Motor gasoline and oxygenate demand 74
Methyl tertiary-butyl ether (MTBE) 76
Producing companies 76
Salient statistics 77
Consumption 77
ETBE 78
Other oxygenates 79
Ethanol 79
Methanol 79
TAME 80
Other fuel oxygenates 80
Middle East 80
Motor gasoline and oxygenate demand 80
Methyl tertiary-butyl ether (MTBE) 82
Producing companies 82
Salient statistics 83
Consumption 84
ETBE 85
Other oxygenates 85
Ethanol 85
Methanol 86
TAME 86
Africa 86
Motor gasoline and oxygenate demand 86
Methyl tertiary-butyl ether (MTBE) 88
Producing companies 88
Salient statistics 88
ETBE 89
Other oxygenates 89
Ethanol 89
Methanol 90
TAME 90
Other ethers 90
Indian Subcontinent 90
Motor gasoline and oxygenate demand 90
MTBE 92
Ethyl tertiary-butyl ether (ETBE) 94
Other oxygenates 94
Ethanol 94
Methanol 95
TAME 95
Northeast Asia 95
Overview 96
Motor gasoline and oxygenate demand 96
Methyl tertiary-butyl ether (MTBE) 97
Capacity 97
Salient statistics 98
Consumption 98
Ethyl tertiary-butyl ether (ETBE) 100
Other oxygenates 101
Ethanol 101
Methanol 101
TAME 102
Mainland China 102
Motor gasoline and oxygenate demand 102
Methyl tertiary-butyl ether (MTBE) 104
Producing companies 104
Salient statistics 109
Ethyl tertiary-butyl ether (ETBE) 109
Other oxygenates 109
Ethanol 109
Methanol 110
TAME 112
TBA 112
Japan 112
Motor gasoline demand and characteristics 112
Methyl tertiary-butyl ether (MTBE) 114
Ethyl tertiary-butyl ether (ETBE) 115
Other oxygenates 117
Ethanol 117
Lead alkyl antiknock mixes 117
South Korea 117
Motor gasoline demand and characteristics 117
Methyl tertiary-butyl ether (MTBE) 119
ETBE and TAME 120
Other oxygenates 120
Ethanol 120
Methanol 120
Taiwan 120
Motor gasoline demand and characteristics 120
MTBE 122
ETBE and TAME 123
Other oxygenates 123
Ethanol 123
Methanol 123
Southeast Asia 123
Motor gasoline demand and characteristics 123
MTBE 125
Producing companies 125
Salient statistics 126
Consumption 127
ETBE 128
Other oxygenates 128
Ethanol 128
Methanol 129
TAME 129
Terminology130
Additional resources132
Revisions133
Data Workbook134

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